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7748173 
Journal Article 
Ion-solvent and ion-ion interactions at high concentration LiClO4 solutions in acetone 
Xuan, XP; Wang, JJ; Zhao, Y; Zhuo, KL 
2005 
Yes 
Huaxue Xuebao / Acta Chemica Sinica
ISSN: 0567-7351 
63 
18 
1693-1698 
Chinese 
WOS:000232089800011 
The Infrared and Raman spectra of LiClO4/acetone solutions have been investigated from diluted to high concentrations. It was found that the C=O and C-C stretches of acetone were very sensitive to the interaction between Li+ and acetone molecules. Apparent solvation numbers of 1.9-3.4 for Li+ have been inferred at different molalities of LiClO4 and the carbonyl group was suggested to be the main bonding site. The ClO 4- bands reveal the evidence for the presence of contact ion pair and its dimer. The association constants of LiC1O4 in acetone has been calculated and compared with the data obtained from conductivity measurements. 
lithium perchlorate; acetone; ion solvation; ion association; raman spectroscopy; infrared spectroscopy