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HERO ID
7749528
Reference Type
Journal Article
Title
Comparative study of LiBF4, LiAsF6, LiPF6, and LiClO4 as electrolytes in propylene carbonate-diethyl carbonate solutions for Li/LiMn(2)O(4)cells
Author(s)
Moumouzias, G; Ritzoulis, G; Siapkas, D; Terzidis, D
Year
2003
Is Peer Reviewed?
Yes
Journal
Journal of Power Sources
ISSN:
0378-7753
Volume
122
Issue
1
Page Numbers
57-66
Language
English
DOI
10.1016/S0378-7753(03)00348-3
Web of Science Id
WOS:000184200900007
Abstract
The specific conductances of LiClO4, LiPF6 and LiAsF6 in concentrated solutions of propylene carbonate (PC)-diethyl carbonate (DEC) mixtures at 15, 20, 25, 30, 35 and 40°C were measured and the data were treated with an empirical equation. Specific conductances, against concentration, temperature, and solvent composition plots are given, as well as concentration that corresponds to the maximum specific conductance, against concentration. Activation energies were also calculated from temperature dependence of specific conductance. The three salts mentioned above, as well as LiBF4, were tested as electrolyte solutions with PC-DEC, in Li/Li1.05Mn2O4 cells. © 2003 Elsevier Science B.V. All rights reserved.
Keywords
propylene carbonate; diethyl carbonate; conductances; batteries; spinet
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