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HERO ID
7756609
Reference Type
Journal Article
Title
SOLUBILITY AND SOLVATE FORMATION OF LITHIUM PERCHLORATE IN LOWER NITRILES
Author(s)
Tomkins, RPT; Turner, PJ
Year
1975
Is Peer Reviewed?
Yes
Journal
Journal of Chemical and Engineering Data
ISSN:
0021-9568
EISSN:
1520-5134
Volume
20
Issue
1
Page Numbers
50-52
Language
English
DOI
10.1021/je60064a008
Web of Science Id
WOS:A1975V274900014
Abstract
Solubility data for LiClO4 in acetonitrile and propionitrile are determined by use of cooling curve methods adapted for nonaqueous solvents. Partial phase diagrams for these systems are presented. A distinct dystectic corresponding to the compound LiClO4·4MeCN is obtained in the acetonitrile system with a less pronounced dystectic appearing in the propionitrile system. Results are discussed in terms of ion-solvent interactions. © 1975, American Chemical Society. All rights reserved.
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