NEW COORDINATION MODE OF 4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONATE(2-) IN POLYNUCLEAR GOLD(I) COMPLEXES - CRYSTAL-STRUCTURES OF [AU3(MU(3)-C3S5)(PPH3)3]CLO4 AND [AU4(MU-C3S5)2(MU-PH2PCH2PPH2)2] | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

7762857

Reference Type

Journal Article

Title

NEW COORDINATION MODE OF 4,5-DIMERCAPTO-1,3-DITHIOLE-2-THIONATE(2-) IN POLYNUCLEAR GOLD(I) COMPLEXES - CRYSTAL-STRUCTURES OF [AU3(MU(3)-C3S5)(PPH3)3]CLO4 AND [AU4(MU-C3S5)2(MU-PH2PCH2PPH2)2]

Author(s)

Ito, T; Bennett, JG; Lawson, K; Cerrada, IK; Laguna, A; Laguna, M; Jones, PG

Year

1994

Is Peer Reviewed?

Journal

Journal of the Chemical Society. Dalton Transactions
ISSN: 1472-7773
EISSN: 1364-5447

Issue

Page Numbers

1325-1326

DOI

10.1039/dt9940001325

Web of Science Id

WOS:A1994NH66100025

Abstract

The ligand 4,5-dimercapto-1,3-dithiole-2-thionate(2-) (C3S52-) has been transferred from [NEt4]2-[Zn(C3S5)2] to gold(I) centres. affording di-, tri- or tetra-nuclear complexes containing the C3S52- ligand in unprecedented mu- or mu3-bridging forms.