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HERO ID
7906202
Reference Type
Journal Article
Title
Kinetics and mechanism of the oxidation of ortho-substituted benzyl alcohols by pyridinium dichromate
Author(s)
Kabilan, S; Girija, R
Year
2000
Is Peer Reviewed?
1
Journal
Oxidation Communications
ISSN:
0209-4541
Volume
23
Issue
1
Page Numbers
29-33
Language
English
Web of Science Id
WOS:000086309500003
Abstract
The kinetics and mechanism of the oxidation of benzyl alcohol and some ortho-substututed benzyl alcohols by pyridinium dichromate (PDC) in the presence of trichloroacetic acid (TCA) in 100% acetonitrile medium have been studied. The product of oxidation has been identified as the corresponding benzaldehyde. The stoichiometry of the reaction is found to be 1.5:1. The reaction is first order each in substrate and oxidant concentrations. The mechanism of oxidation varies with the nature of the chromium (VI) species and the solvent used.
Keywords
benzyl alcohol; trichloroacetic acid; kinetics; mechanism; PCD; oxidation
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