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7928199 
Journal Article 
Synthesis of isosorbide-based polycarbonates via melt polycondensation catalyzed by quaternary ammonium ionic liquids 
Sun, Wei; Xu, Fei; Cheng, W; Sun, J; Ning, G; Zhang, S 
2017 
1 
Chinese Journal of Catalysis
ISSN: 1872-2067 
38 
5 
908-917 
English 
WOS:000402346400016 
A series of quaternary ammonium ionic liquids (ILs) were synthesized and employed as catalysts for the production of poly(isosorbide carbonate) (PIC) from diphenyl carbonate and isosorbide via a melt polycondensation process. The relationship between the anions of the ILs and the catalytic activities was investigated, and the readily-prepared IL tetraethylammonium imidazolate (TEAI) was found to exhibit the highest catalytic activity. After optimizing the reaction conditions, a PIC with a weight-average molecular weight (Mw) of 25600 g/mol was obtained, in conjunction with an isosorbide conversion of 92%. As a means of modifying the molecular flexibility and thermal properties of the PIC, poly(aliphatic diol-co-isosorbide carbonate)s (PAIC)s were successfully synthesized, again using TEAI, and polymers with Mw values ranging from 29000 to 112000 g/mol were obtained. 13C NMR analyses determined that the PAIC specimens had random microstructures, while differential scanning calorimetry demonstrated that each of the PAICs were amorphous and had glass transition temperatures ranging from 50 to 115℃. Thermogravimetric analyses found Td-5% values ranging from 316 to 332℃ for these polymers. Based on these data, it is evident that the incorporation of linear or cyclohexane-based diol repeating units changed the thermal properties of the PIC. 2017, Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. All rights reserved. 
Quaternary ammonium ionic liquid catalyst; Isosorbide; Polycarbonate; Melt polycondensation; Aliphatic diol