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HERO ID
7932775
Reference Type
Journal Article
Title
Preparation, characterization and catalytic properties of CuPC/Y nano-composite
Author(s)
Yang, HX; Li, RF; Xie, KC
Year
2002
Is Peer Reviewed?
1
Journal
Studies in surface science and catalysis
ISSN:
0167-2991
Publisher
Elsevier Inc.
Book Title
Studies in Surface Science and Catalysis
Volume
141
Page Numbers
575-582
Language
English
DOI
10.1016/s0167-2991(02)80592-4
Web of Science Id
WOS:000180926800073
Abstract
Well-crystallized CuPC/zeolite Y nano-composite of average particle size less than 80nm (denoted as CuPC/nano-Y) has been successfully synthesized via zeolite synthesis route. The nano-zeolite host was confirmed by the XRD and TEM. The CuPC complexes entrapped in the nano-hosts were characterized by XRD, TEM, FTIR, TG/DTA, ICP and UV-vis. CuPC/Y samples with different particle sizes in micro-scale were also synthesized by adjusting the synthesis conditions. Under the mild situation (60°C, latm), CuPC in nano-Y exhibits the catalytic activity 2.1 times higher than CuPC in normal Y with particle size of 500nm for the liquid phase oxidation of cyclohexane using aqueous H2O2 (30wt.%) as the oxidant.
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