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7938104 
Journal Article 
Study on the initial product channels of cyclohexane pyrolysis 
Braun-Unkhoff, M; Naumann, C; Frank, P 
2004 
0 
Abstracts of Papers of the American Chemical Society
ISSN: 0065-7727 
227 
U1096-U1096 
English 
WOS:000223655603830 
Very small initial concentrations of cyclohexane (1-11 ppm) were heated behind reflected shock waves at 1180-1900 K at 1.5 and 2 bar. The experiments were performed in a high purity shock tube applying a very sensitive detection method, the ARAS technique. From the experimental data, the molecular channel proceeds much slower than considered up to now, whereas for the H-atom elimination pathway, rate coefficients were found, which are similar to those of the molecular channel. This is an abstract of a paper presented at the 227th ACS National Meeting (Anaheim, CA 3/28/2004-4/1/2004).