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HERO ID
7945346
Reference Type
Journal Article
Title
Ionic hydrogenation of dihydroxynaphthalenes with cyclohexane in the presence of aluminum bromide
Author(s)
Ostashevskaya, LA; Koltunov, KY; Repinskaya, IB
Year
2000
Is Peer Reviewed?
1
Journal
Russian Journal of Organic Chemistry
ISSN:
1070-4280
EISSN:
1608-3393
Volume
36
Issue
10
Page Numbers
1474-1477
Language
English
Web of Science Id
WOS:000168062000009
Abstract
Reactions of 1,5-, 1,6-, 1,7-, 2,6-, and 2,7-dihydroxynaphthalenes with cyclohexane in the presence of excess aluminum bromide in methylene bromide quantitatively yield 5-, 6-, and 7-hydroxynaphthalen-1-ones and 6- and 7-hydroxynaphthalen-2-ones, respectively. Tricationic C-protonated complexes are presumed to be reactive intermediates in these processes.
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