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7947048 
Journal Article 
Particle-size-dependent upconversion luminescence of NaYF4: Yb, Er nanoparticles in organic solvents and water at different excitation power densities 
Kraft, M; Wuerth, C; Muhr, V; Hirsch, T; Resch-Genger, Ute 
2018 
1 
Nano Research
ISSN: 1998-0124 
11 
12 
6360-6374 
English 
WOS:000454367500022 
A systematic study of the luminescence properties of monodisperse β-NaYF4: 20% Yb3+, 2% Er3+ upconversion nanoparticles (UCNPs) with sizes ranging from 12–43 nm is presented utilizing steady-state and time-resolved fluorometry. Special emphasis was dedicated to the absolute quantification of size- and environment-induced quenching of upconversion luminescence (UCL) by high-energy O–H and C–H vibrations from solvent and ligand molecules at different excitation power densities (P). In this context, the still-debated population pathways of the 4F9/2 energy level of Er3+ were examined. Our results highlight the potential of particle size and P value for color tuning based on the pronounced near-infrared emission of 12 nm UCNPs, which outweighs the red Er3+ emission under “strongly quenched” conditions and accounts for over 50% of total UCL in water. Because current rate equation models do not include such emissions, the suitability of these models for accurately simulating all (de)population pathways of small UCNPs must be critically assessed. Furthermore, we postulate population pathways for the 4F9/2 energy level of Er3+, which correlate with the size-, environment-, and P-dependent quenching states of the higher Er3+ energy levels. [Figure not available: see fulltext.]. 2018, Tsinghua University Press and Springer-Verlag GmbH Germany, part of Springer Nature. 
upconversion; nanoparticle; quenching; diameter; water; cyclohexane