REACTION OF 3,3-DICHLOROPENTANE-2,4-DIONE WITH AROMATIC-ALDEHYDES UNDER THE CONDITIONS OF DARZENS REACTION | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

7952445

Reference Type

Journal Article

Title

REACTION OF 3,3-DICHLOROPENTANE-2,4-DIONE WITH AROMATIC-ALDEHYDES UNDER THE CONDITIONS OF DARZENS REACTION

Author(s)

Mamedov, VA; Berdnikov, EA; Litvinov, IA; Kuzmina, LG

Year

1995

Is Peer Reviewed?

Journal

Russian Chemical Bulletin
ISSN: 1066-5285
EISSN: 1573-9171

Volume

Issue

Page Numbers

1247-1251

Language

English

DOI

10.1007/BF00700897

Web of Science Id

WOS:A1995RZ93000017

Abstract

3,3-Dichloropentane-2,4-dione reacts with aromatic aldehydes under the conditions of Darzens reaction to give 4-acetoxy-4-aryl-3,3-dichlorobutan-2-ones, the products of insertion into the σ-C-C bond. The reaction of ethyl dichloroacetylacetate with benzaldehyde yields a derivative of tricyclo[5.1.0.03,5]octane, rather than 2,6-bis(1′-chlorobenzylidene)cyclohexane-1,4-dione, as the by-product. 1995, Plenum Publishing Corporation. All rights reserved.

Keywords

DARZENS REACTION, 3,3-DICHLOROPENTANE-2,4-DIONE; INSERTION REACTION; 3,3-DICHLOROBUTAN-2-ONE; CYCLOHEXANE-1,4-DIONE; TRICYCLOOCTANE; X-RAY STRUCTURAL INVESTIGATION