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HERO ID
7957469
Reference Type
Journal Article
Title
Densities and Viscosities of Ternary Mixtures of Cyclohexane plus Cyclohexanone plus Some Alkyl Acetates at 298.15 K
Author(s)
Roy, MN; Sarkar, BK; Sinha, B
Year
2009
Is Peer Reviewed?
Yes
Journal
Journal of Chemical and Engineering Data
ISSN:
0021-9568
EISSN:
1520-5134
Volume
54
Issue
3
Page Numbers
1076-1083
Language
English
DOI
10.1021/je8007217
Web of Science Id
WOS:000264197700069
Abstract
The excess molar volumes, VEm and viscosity deviations, Δη, were calculated from the measured density and viscosity data over the whole composition range for the ternary systems of cyclohexane (CHX) + cyclohexanone (CHXN) + methyl acetate (MA), ethyl acetate (EA), and propyl acetate (PA) and the constituent binary mixtures of cyclohexane or cyclohexanone + methyl acetate, ethyl acetate, propyl acetate, and cyclohexane or cyclohexanone at 298.15 K under atmospheric pressure. The excess or deviation properties of the binary and ternary systems were fitted to Redlich - Kister and Cibulka equations, respectively. The excess or deviation properties were found to be either negative or positive depending on the molecular interactions and the nature of liquid mixtures. 2009 American Chemical Society.
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