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7957946 
Journal Article 
CHAIN TERMINATION IN LIQUID-PHASE SULFOXIDATION OF CYCLOHEXANE 
Komissarov, VD; Khalimov, RF 
1975 
1 
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230 
24 
9 
1849-1851 
English 
WOS:A1975BS52700011 
1. The kinetics of the liquid-phase sulfoxidation of cyclohexane, initiated by dicyclohexylperoxidicarbonate at 75°, was studied. 2. A mechanism was proposed for the process, including a reaction of the cyclohexyl radical with oxygen and of the cyclohexylsulfonyl radical with the wall of the reactor as reactions of chain termination. The relative rate constants of the reaction were determined. 1976 Plenum Publishing Corporation.