Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
7993172
Reference Type
Journal Article
Title
Oxidative enzymatic alkene cleavage: indications for a nonclassical enzyme mechanism
Author(s)
Lara, M; Mutti, FG; Glueck, SM; Kroutil, W
Year
2009
Is Peer Reviewed?
Yes
Journal
Journal of the American Chemical Society
ISSN:
0002-7863
EISSN:
1520-5126
Volume
131
Issue
15
Page Numbers
5368-5369
Language
English
PMID
19323520
DOI
10.1021/ja8097096
Web of Science Id
WOS:000265268100003
Abstract
An enzyme preparation of Trametes hirsuta cleaves alkenes following neither the classical dioxygenase mechanism nor via a monooxygenase mechanism. A catalytic cycle for an alternative enzymatic alkene cleavage was proposed, whereby two oxygen atoms derived from two different oxygen molecules are incorporated into the product(s).
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity