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Citation
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HERO ID
8111318
Reference Type
Journal Article
Title
Synthesis and transformation of (dimydroanthrylene) naphthohydroquinone (contribution to the stereochemistry of catalysis)
Author(s)
Balandin, AA; Klabunovskii, EI; Antik, LV
Year
1961
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Publisher
Kluwer Academic Publishers-Plenum Publishers
Volume
10
Issue
12
Page Numbers
2046-2048
Language
English
DOI
10.1007/BF01182952
Abstract
1. As a result of the hydrogenation of the quinone (I) over Raney nickel there was formed a previously undescribed readily oxidizable hydroquinone (III), which was characterized as the quinhydrone, the diacetic ester, and the bis(phenylurethan). 2. In the condensation of anthracene with 1,4-naphthoquinone in acetic anhydride, the formation of the diacetate (IV) is accompanied by oxidation of the hydroquinone (III) to the quinone (I) by unchanged 1,4-naphthoquinone. Under the conditions of the reaction the latter gives 1,4-naphthalenediol diacetate. © 1962 Consultants Bureau Enterprises, Inc.
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