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HERO ID
8152239
Reference Type
Journal Article
Title
Synthesis of A1PO4, LaPO4 and KTiOPO4 by flash combustion
Author(s)
Arul Dhas, N; Patil, KC
Year
1993
Is Peer Reviewed?
Yes
Journal
Journal of Alloys and Compounds
ISSN:
0925-8388
Volume
202
Issue
1-2
Page Numbers
137-141
Language
English
DOI
10.1016/0925-8388(93)90532-R
Abstract
Fine particle AlPO4, LaPO4 and KTiOPO4 have been prepared by the flash combustion of aqueous solutions containing metal nitrate, ammonium hydrogen phosphate, ammonium nitrate or ammonium perchlorate and carbohydrazide or tetraformal trisazine. When rapidly heated at 400 °C, the solution containing the redox mixtures ignites to undergo self-propagating, gas-producing, exothermic reactions. Formation of crystalline phosphates was confirmed by powder X-ray diffraction patterns and IR spectra. The metal phosphates formed are fine and have 20-78 m2 g-1 surface area. © 1993.
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