Health & Environmental Research Online (HERO)


Print Feedback Export to File
8156055 
Journal Article 
Palladium catalyzed cross-coupling reactions for phosphorus-carbon bond formation 
Schwan, AL 
2004 
Yes 
Chemical Society Reviews
ISSN: 0306-0012
EISSN: 1460-4744 
33 
4 
218-224 
English 
15103403 
WOS:000221668400003 
Underappreciated in the realm of palladium catalyzed cross-coupling chemistry is the formation of phosphorous-carbon bonds. This tutorial review summarises a collection of important contributions in the area, providing a flavour of the many types of phosphorus species that are participants in palladium catalyzed phosphorus-carbon bond formation. Recent developments include the usage of the cross-coupling reaction for preparation of phosphine ligands and the involvement of low molecular weight phosphinic acid derivatives for the synthesis of unsaturated phosphinic and phosphonic acid derivatives. Mechanistic cycles are offered in some instances. Stereochemical issues are addressed where applicable. The literature is covered to mid 2003.