A niobium-mediated cycle producing phosphorus-rich organic molecules from white phosphorus (P4) through activation, functionalization, and transfer reactions | Health & Environmental Research Online (HERO)

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Citation
Tags

HERO ID

8198272

Reference Type

Journal Article

Title

A niobium-mediated cycle producing phosphorus-rich organic molecules from white phosphorus (P4) through activation, functionalization, and transfer reactions

Author(s)

Cossairt, BM; Cummins, CC

Year

2008

Is Peer Reviewed?

Yes

Journal

Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773

Publisher

WILEY-V C H VERLAG GMBH

Location

WEINHEIM

Volume

Issue

Page Numbers

8863-8866

Language

English

PMID

18855962

DOI

10.1002/anie.200803971

Web of Science Id

WOS:000260878700015

URL

https://onlinelibrary.wiley.com/doi/10.1002/anie.200803971
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Abstract

(Figure Presented) PROMs: Niobium-mediated aggregation of two molecules of white phosphorus and subsequent exploitation of niobium-phosphorus multiple bonding leads to the synthesis of phosphorus-rich organic molecules as Diels-Alder adducts (see scheme; orange P, white C). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

Keywords

Cluster compounds; Diels-Alder reaction; Diphosphenes; Niobium; Phosphorus