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Citation
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HERO ID
8205255
Reference Type
Journal Article
Title
Studies on the luminescence properties of cerium co-doping on Ca2 MgSi2 O7 :Eu2+ phosphor by solid-state reaction method
Author(s)
Sahu, IP; Bisen, DP; Murthy, KVR; Tamrakar, RK; ,
Year
2017
Is Peer Reviewed?
1
Journal
Luminescence
ISSN:
1522-7235
EISSN:
1522-7243
Publisher
WILEY
Location
HOBOKEN
Page Numbers
1263-1276
Language
English
PMID
28556399
DOI
10.1002/bio.3320
Web of Science Id
WOS:000412673600023
URL
https://onlinelibrary.wiley.com/doi/10.1002/bio.3320
Exit
Relationship(s)
has retraction
8055802
Retraction: Ishwar Prasad Sahu, D. P. Bisen, K. V. R. Murthy, R. K. Tamrakar (2017)
Abstract
Ca2 MgSi2 O7 :Ce3+ , Ca2 MgSi2 O7 :Eu2+ and Ca2 MgSi2 O7 :Eu2+ ,Ce3+ phosphors were prepared using the solid-state reaction method. The crystal structures of the sintered phosphors were of melilite type, which has a tetragonal crystallography. The chemical compositions of the sintered phosphors was confirmed by energy dispersive X-ray spectroscopy. The different thermoluminescence kinetic parameters [activation energy (E), frequency factor (s) and order of the kinetics (b)] of these phosphors were evaluated and compared using the peak shape method. Under ultraviolet excitation, the emission spectra of both Ca2 MgSi2 O7 :Eu2+ and Ca2 MgSi2 O7 :Eu2+ ,Ce3+ phosphors were composed of a broad emission band peaking at 530 nm. When the Ca2 MgSi2 O7 :Eu2+ phosphor is co-doped with Ce3+ ions, photoluminescence, afterglow and mechanoluminescence intensity was strongly enhanced. Ca2 MgSi2 O7 :Eu2+ showed some afterglow with a short persist time. On incorporation of Ce3+ , efficient energy transfer from Ce3+ to Eu2+ was found and the emission intensity of Eu2+ was enhanced. The mechanoluminescence intensities of Ca2 MgSi2 O7 :Ce3+ , Ca2 MgSi2 O7 :Eu2+ and Ca2 MgSi2 O7 :Eu2+ ,Ce3+ phosphors increased proportionally increased with the increase in impact velocity, which suggests that these phosphors can be used as sensors to detect stress in an object.
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