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HERO ID
8216035
Reference Type
Journal Article
Title
Photon-quantitative reaction of a dithiazolylarylene in solution
Author(s)
Fukumoto, S; Nakashima, T; Kawai, T; ,
Year
2011
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
50
Issue
7
Page Numbers
1565-1568
Language
English
PMID
21308905
DOI
10.1002/anie.201006844
Abstract
Ready for action: An excellent quantum yield was observed for a photocoloration reaction of a photochromic molecule based on a triangular terarylene structure. The molecule is brought into a conformation favorable for photocyclization by multiple intramolecular interactions, including CHi-N hydrogen bonding and Si-N and CHi-Ï interactions (see picture). © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
heterocycles; hydrogen bonds; photochromism; supramolecular chemistry
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