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8256493 
Journal Article 
Stereoselective synthesis of bicyclic nitrocyclopropanes by a radical-anion domino reaction 
Kamimura, A; Kadowaki, A; Yoshida, T; Takeuchi, R; Uno, H; , 
2009 
Yes 
Chemistry: A European Journal
ISSN: 0947-6539
EISSN: 1521-3765 
15 
40 
10330-10334 
English 
19746489 
A novel one-step radical-ionic cyclopropanation was carried out to prepare aza- or oxabicyclo[3.1.0]hexane from β-nitroamides or β-nitroethers in a stereoselective manner (see scheme). The present procedure involves a higher-order domino process that includes one-electron oxidationradical cyclization-intramolecular SN2 reaction. © 2009 Wiley-VCH Verlag GmbH & Co. KGaA. 
Cyclopropanes; Domino reactions; Oxidation; Radical cyclization; Stereoselective reaction