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8257423 
Journal Article 
Calcium-catalyzed friedel-crafts alkylation at room temperature 
Niggemann, M; Meel, MJ 
2010 
Yes 
Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773 
49 
21 
3684-3687 
English 
Chemical Equatation Representation A novel calcium catalyst was found to efficiently functionalize electron-rich arenes with secondary and tertiary benzylic, propargylic, and allylic alcohols under very mild reaction conditions. The new catalyst system significantly enlarges the scope of the reaction, which was previously limited except for the few examples with secondary benzylic alcohols. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA. 
Alcohols; Allylic compounds; Arylation; Calcium; Friedel-crafts reaction