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8305154 
Journal Article 
Superclusters: a host-guest complex with a cyclic array of three bridged MoFe3S4 clusters 
Koutmos, M; Coucouvanis, D; , 
2004 
Yes 
Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773 
43 
38 
5023-5025 
English 
15384123 
Three reversible reductions are observed for a new cyclic tricubane cluster. In the solid state, the cluster displays a large, electron-rich pocket containing an encapsulated Et4N+ ion (see structure). These characteristics might allow the use of this cluster as a multielectron reducing agent. 
Cluster compounds; Host-guest chemistry; Nitrogenase; Reduction; S ligands