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HERO ID
8306416
Reference Type
Journal Article
Title
Gold-catalyzed intermolecular addition of carbonyl compounds to 1,6-enynes
Author(s)
Schelwies, M; Dempwolff, AL; Rominger, F; Helmchen, G; ,
Year
2007
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
46
Issue
29
Page Numbers
5598-5601
Language
English
PMID
17583886
DOI
10.1002/anie.200701378
Abstract
(Chemical Equation Presented) Gold rush: Gold catalysis remains a highly attractive field of research for the discovery of new reaction types. A novel intermolecular addition of aldehydes and ketones to enynes leads to the diastereoselective synthesis of 2-oxabicyclo[3.1.0]hexanes (see scheme). © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
Keywords
Aldehydes; Cyclization; Cyclopropane; Gold; Homogeneous catalysis
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