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HERO ID
8308802
Reference Type
Journal Article
Title
Crystal structure of 7-chloro-2,3,3a,4,9,9a-hexahydro-3,9,9-trimethyl-5-nitro-1H-cyclopenta[b]quinoline
Author(s)
Sridhar, G; Mohammed Bilal, I; Easwaramoorthy, D; Kutti Rani, S; Anand Solomon, K
Year
2016
Is Peer Reviewed?
0
Journal
International Journal of ChemTech Research
ISSN:
0974-4290
Publisher
Sphinx Knowledge House
Volume
9
Issue
6
Page Numbers
362-366
Language
English
Abstract
The title compound C16 H19 Cl N2 O2 is the product of reaction between 4- chloroaniline and melonal in the presence of cupric nitrate and HCl. The product is the resultant of nitration of the aromatic ring and electrophilic aromatic cyclization. The heterocyclic ring at the center adopts a half-chair conformation and the five-membered ring has an envelope conformation. The crystal structure is stabilized by intra-molecular hydrogen bond. The molecular structure is stabilized by an intra-molecular NâHâ¯O hydrogen bond, with an S (6) ring motif. © 2016, Sphinx Knowledge House. All rights reserved.
Keywords
Crystal structure; NâHâ¯O hydrogen bond; Quinolone
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