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HERO ID
8311000
Reference Type
Journal Article
Title
Investigation of the hydrogenation of p-carboxybenzaldehyde in the presence of Pd-, Ru-, and Rh -catalysts
Author(s)
Freidlin, LK; Litvin, EF; Gurskii, RN; Oparina, GK; Istratova, RV
Year
1972
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Publisher
Kluwer Academic Publishers-Plenum Publishers
Volume
21
Issue
8
Page Numbers
1682-1685
Language
English
DOI
10.1007/BF00851178
Abstract
1. The hydrogenation of p-carboxybenzaldehyde proceeds according to zero order with respect to the substrate and according to first order with respect to H2. 2. On Pd-catalysts, hydrogenation is accompanied by subsequent hydrogenolysis of the C-OH bond of the carbinol formed. 3. On a Rh-catalyst hydrogenolysis proceeds extremely slowly, while on a Ru-catalyst p-carboxy-benzyl alcohol is selectively formed. © 1973 Consultants Bureau.
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