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8329841 
Journal Article 
Synthesis of (1α,5α,6α)-6-Amino-3-azabicyclo[3.1.0]hexane, a Novel Achiral Diamine 
Brighty, KE; Castaldi, MJ 
1996 
Synlett
ISSN: 0936-5214
EISSN: 1437-2096 
Georg Thieme Verlag 
1996 
11 
1097-1099 
English 
Synthesis of (1α,5α,6α)-6-amino-3-azabicyclo[3.1.0]-hexane is described. Ethyl diazoacetate cycloaddition to a pyrroline or maleimide derivative provides the azabicyclohexyl system; amine introduction is then effected using a modified Curtius rearrangement.