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8330156 
Journal Article 
Etudes cinétiques dans le domaine des dérivés polycycliques aromatiques VII. Réactions d'échange SN2 et de solvolyse des chlorométhyl‐1‐,‐3 et 4‐pyrènes 
Planchon, M; Fierens, PJC; Martin, RH 
1959 
Yes 
Helvetica Chimica Acta
ISSN: 0018-019X 
42 
2 
517-522 
French 
ARRHENIUS parameters have been determined (a) for the solvolysis of 1‐,3‐ and 4‐chloromethylpyrene in different solvents (Table 11) and (b) for the S,2 reaction of 1‐ and 4‐chloromethylpyrene with KI in acetone (Table IV). Taking into account previous results, it is shown that 3‐chloromethylpyrene has an apparently abnormally high rate constant in solvolysis reactions. Copyright © 1959 Verlag GmbH & Co. KGaA, Weinheim