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HERO ID
8331154
Reference Type
Journal Article
Title
POLYESTERS BEARING PENDANT ANTHRYL AND PYRENYL GROUPS FROM THIOESTERS OF DICARBOXYLIC ACIDS
Author(s)
Sato, K; Hayashi, N; Tazuke, S
Year
1977
Is Peer Reviewed?
1
Journal
Journal of Polymer Science, Polymer Letters Edition
ISSN:
0360-6384
Publisher
JOHN WILEY & SONS INC
Location
NEW YORK
Volume
15
Issue
11
Page Numbers
671-674
DOI
10.1002/pol.1977.130151105
Web of Science Id
WOS:A1977EA15100005
Abstract
For the study on the relation between inter- and/or intramolecular interactions and polymer structure both in solution and solid state, the basic requirement is to obtain a series of samples which satisfy the following conditions: (i) availability of systematically modified polymer structures; (ii) versatility of introducing various functional groups; (iii) good solubility in common solvents; (iv) film-forming property for the solid-state study; and (v) high purity of samples permitting precise spectroscopic measurements. In the reported investigation the authors have studied the molecular interactions and functionalities of polymers with special reference to the polymer structures by measuring charge-transfer complex formation, excimer and exciplex formation, fluorescence quenching, and photoreactions of polymers. Various polyesters and, in some cases, polyurethanes were prepared from 2-substituted-1,3-propanediol(I). Experimental data obtained with polycondensation of I with thiophenol esters of dicarboxylic acid without catalysts are tabulated and fluorescence spectra of pyrene polymers, reflecting polymer structure, are included. 13 refs.
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