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HERO ID
8333710
Reference Type
Journal Article
Title
Effective reduction of halogen-containing hydrocarbons by diisobutyl aluminum hydride in the presence of transition metal hydrides
Author(s)
Dzhemilev, UM; Gaisin, RL
Year
1988
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Publisher
Kluwer Academic Publishers-Plenum Publishers
Location
NEW YORK
Volume
37
Issue
10
Page Numbers
2099-2102
Language
English
DOI
10.1007/BF00953413
Web of Science Id
WOS:A1988AK95300003
Abstract
1. An effective reduction of halogen-containing hydrocarbons at the C-Hal bond was carried out by means of i-Bu2AlH in the presence of catalytic amounts of Ti, Zr, and Hf complexes. 2. A partial transformation of halobenzenes and bromocyclohexane into hexane by the action of i-Bu2AlH and catalytic amounts of Cp2TiCl2 under mild conditions was noted for the first time. © 1989 Plenum Publishing Corporation.
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