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8344554 
Journal Article 
Synthesis of 2,5-dibromobenzaldehyde and its reaction with hexylmagnesium bromide 
Shimura, Y; Kawai, T; Minegishi, T 
1993 
Synthesis
ISSN: 0039-7881
EISSN: 1437-210X 
43-44 
English 
2,5-Dibromobenzaldehyde (3) is synthesized by the oxidation of 2,5-dibromotoluene (1) via 2,5-dibromobenzylidene diacetate (2). Grignard reaction of hexylmagnesium bromide with 2 gives the normal addition product, 2,5-dibromo-α-hexylbenzyl alcohol (5) and reduced product, 2,5-dibromobenzyl alcohol (6).