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HERO ID
8347643
Reference Type
Journal Article
Title
A New Method of Preparing the High Explosive RDX
Author(s)
Bachmann, WE; Sheehan, JC
Year
1949
Is Peer Reviewed?
Yes
Journal
Journal of the American Chemical Society
ISSN:
0002-7863
EISSN:
1520-5126
Volume
71
Issue
5
Page Numbers
1842-1845
Language
English
DOI
10.1021/ja01173a092
Abstract
A new synthesis of the high explosive cyclotrimethylenetrinitramine (RDX) is described. From one mole of hexamethylenetetramine it is possible to obtain two moles of RDX by carrying out the nitrolysis at 75° in acetic anhydride in the presence of ammonium nitrate. Two new nitrolysis products of hexamethylenetetramine were discovered. One (HMX) is formed in the RDX reaction; the other (BSX) is produced when the reagents are mixed cold and the temperature is raised slowly. © 1949, American Chemical Society. All rights reserved.
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