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HERO ID
8362412
Reference Type
Journal Article
Title
Kinetics of esterification of benzyl alcohol with acetic acid catalysed by cationâexchange resin (Amberlystâ15)
Author(s)
Roy, R; Bhatia, S
Year
1987
Is Peer Reviewed?
1
Journal
Journal of Chemical Technology and Biotechnology
ISSN:
0268-2575
EISSN:
1097-4660
Volume
37
Issue
1
Page Numbers
1-10
Language
English
DOI
10.1002/jctb.280370103
Abstract
Esterification of benzyl alcohol with acetic acid catalysed by Amberlystâ15 (cationâexchange resin) was carried out in a batch reactor in the liquid phase in the temperature range 328â359 K and at 1 atm. The reaction rate increased with increase in catalyst concentration and reaction temperature. Resin particle size and stirrer speed had virtually no effect on the rate under the experimental conditions. The rate data were correlated with a kinetic model based on homogeneous reaction. The apparent activation energy was found to be 73.3 kJ molâ1 for the formation of benzyl acetate. Copyright © 1987 Society of Chemical Industry
Keywords
acetic acid; benzyl alcohol; cationâexchange resin (Amberlystâ15); Esterification; kinetics
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