1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]-octane chlorochromate (DBDABOCC): A mild and selective reagent for efficient oxidation of organic compounds under non-aqueous conditions | Health & Environmental Research Online (HERO)

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Citation
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HERO ID

8401064

Reference Type

Journal Article

Title

1,4-Dibenzyl-1,4-diazoniabicyclo[2.2.2]-octane chlorochromate (DBDABOCC): A mild and selective reagent for efficient oxidation of organic compounds under non-aqueous conditions

Author(s)

Mohammadpoor-Baltork, I; Hajipour, AR; Ghahramankhani, A

Year

2000

Is Peer Reviewed?

Journal

Indian Journal of Chemistry. Section B
ISSN: 0376-4699
EISSN: 0975-0983

Volume

Issue

Page Numbers

863-866

Language

English

Abstract

The preparation of 1,4-dibenzyl-1,4-diazoniabicyclo[2.2.2]-octane chlorochromate 1 is described. With this reagent benzylic and allylic alcohols are selectively oxidized to their corresponding carbonyl compounds in excellent yields. Oximes, thiols and aromatic amines are also converted to their corresponding carbonyl compounds, disulfides and azo compounds efficiently.