Jump to main content
US EPA
United States Environmental Protection Agency
Search
Search
Main menu
Environmental Topics
Laws & Regulations
About EPA
Health & Environmental Research Online (HERO)
Contact Us
Print
Feedback
Export to File
Search:
This record has one attached file:
Add More Files
Attach File(s):
Display Name for File*:
Save
Citation
Tags
HERO ID
8415616
Reference Type
Journal Article
Title
Synthesis of 1, 2, 4, 5-tetraaminobenzene and its hydrochloride
Author(s)
Jin, N; Liu, W; Jin, T; Chen, H; He, B
Year
2012
Volume
63
Issue
7
Page Numbers
2092-2099
Language
Chinese
DOI
10.3969/j.issn.0438-1157.2012.07.014
Abstract
Based on the current worldwide trend of using 1, 2, 4, 5-tetraaminobenzene (TAB)and its hydrochloride (TAB·4HCl) in new materials and absence of relevant study in China, a new method of synthesizing polymer grade monomer TAB·4HCl was studied, systematic analysis and optimization was made for the synthesis process, and the relationship of the ammonolysis selectivity with pressure and temperature were clarified. The results showed that 4, 6-dinitro-1, 3-phenylenediamine (DADNB) was prepared by double ammonolysis reaction at 1.0 MPa pressure in 1, 4-dioxane solvent from 1, 3-dichloro-4, 6-dinitrobenzene (DCDNB) ammonia as ammonolysis agent, and then hydrogenated in methanol solvent, the solution containing TAB was obtained after the hydrogenation liquid was decolored with active carbon, then TAB·4HCl was obtained by adding hydrochloric acid and concentrating under reduced pressure and filtering, with 99.3% purity and 79.7% total yield. Finally, with synthesis reliability of 99% and good practical value, a plan for solvent recovery and recycling was proposed for commercialization of TAB·4HCl production. © 2012 All Rights Reserved.
Keywords
1, 2, 4, 5-tetraaminobenzene tetrahydrochloride; 1, 3-dichloro-4, 6-dinitrobenzene; 4, 6-dinitro-1, 3-phenylenediamine; Ammonolysis selectivity
Tags
PPRTV
•
1,3-Dinitrobenzene 2021
Literature Search June 2021
Scopus (July 2021)
Home
Learn about HERO
Using HERO
Search HERO
Projects in HERO
Risk Assessment
Transparency & Integrity