Health & Environmental Research Online (HERO)


Print Feedback Export to File
8417893 
Journal Article 
Reactions for the formation of alkyl(aryl)chlorosilanes by direct synthesis - Communication 11. Selective formation of ethyldichlorosilane by the addition of calcium silicide to silicon-copper contact masses 
Moskovtsev, VV; Golubtsov, SA; Andrianov, KA; Turetskaya, RA 
1973 
1 
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230 
Kluwer Academic Publishers-Plenum Publishers 
22 
3 
588-591 
English 
1. A reactive complex of ethylene (decomposition product of ethyl chloride) and active silicon is formed under the conditions of the reaction of ethyl chloride with a silicon-copper contact mass that contains calcium suicide. 2. The theory was expressed that this complex takes part in the formation of ethyldichlorosilane, which is in agreement with the rules for the change in the composition of the reaction products during the synthesis process. © 1973 Consultants Bureau.