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8431310 
Journal Article 
Formation of alkyl (or aryl) chlorosilanes by the direct reaction of alkyl (or aryl) chlorides with silicon - Communication 2. Effect of hydrogen chloride on the process leading to the formation of chloroethylsilanes 
Andrianov, KA; Turetskaya, RA; Golubtsov, SA; Trofimova, IV 
1962 
1 
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230 
Kluwer Academic Publishers-Plenum Publishers 
11 
10 
1696-1701 
English 
1. Under the conditions of the direct synthesis of chloroethylsilanes ethyl chloride undergoes decomposition with liberation of hydrogen chloride, which reacts with silicon and determines the formation of dichloroethylsilane and trichlorethylsilane in the reactions of ethyl chloride with silicon-copper contact masses. 2. On the basis of the proposed scheme of reactions leading to the formation of dichloroethylsilane and trichloroethylsilane, an explanation is given of the increase in the yields of products resulting from the introduction of hydrogen chloride, hydrogen, or water into the ethyl chloride. © 1963 Consultants Bureau.