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HERO ID
8431464
Reference Type
Journal Article
Title
Interaction of triethyl phosphite with isopropyl iodide and tert-butyl chloride at high pressures
Author(s)
Gonikberg, MG; Fainshtein, IZ
Year
1967
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Publisher
Kluwer Academic Publishers-Plenum Publishers
Volume
16
Issue
3
Page Numbers
516-519
Language
English
DOI
10.1007/BF00905983
Abstract
1. The ratio of the rate constants of the interaction of triethyl phosphite with isopropyl iodide and the simultaneous parallel-successive isomerization of triethyl phosphite was determined. At 100° in toluene solution and a pressure of 4000 kg/cm2, the rate constant of the first sterically hindered reaction is approximately 60 times lower than the rate constant of the second reaction. 2. The interaction of triethyl phosphite with tert-butyl chloride at the temperatures 100-200° and pressures up to 12,000 kg/cm2 does not lead to the formation of the diethyl ester of tert-butylphosphinic acid. Diethyl esters of phosphorous and ethylphosphinic acids, ethyl chloride, isobutylene, its dimers and trimers, and higher molecular products of secondary reactions were found in the reaction products. © 1967 Consultants Bureau.
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