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HERO ID
8431485
Reference Type
Journal Article
Title
Autocatalytic character of reaction of diethylaluminum chloride with ethyl chloride
Author(s)
Matkovskii, PE; Russiyan, LN; Gerasina, MP; Brikenshtein, KM; Chirkov, NM
Year
1971
Is Peer Reviewed?
1
Journal
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN:
0568-5230
Publisher
Kluwer Academic Publishers-Plenum Publishers
Volume
20
Issue
12
Page Numbers
2657-2658
Language
English
DOI
10.1007/BF00853646
Abstract
1. Diethylaluminum chloride in the presence of olefins, butadiene or styrene, in the temperature range 20-40°, reacts with ethyl chloride, being converted to aluminum chloride. 2. The reaction has a well-defined autocatalytic character. The autocatalysis during the course of the transformations is determined by the reaction of diethylaluminum chloride with the formed aluminum trichloride. © 1972 Consultants Bureau.
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