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8443768 
Journal Article 
The reaction between amines and 1-chloro-2:4-dinitrobenzene 
Brady, OL; Cropper, FR 
1950 
Yes 
Journal of the Chemical Society
ISSN: 0368-1769 
507-516 
English 
The reaction of a number of alkylamines and dialkylamines with chlorodinitrobenzene has been studied kinetically, and it has been found that there is a remarkable difference between the rate constants for different amines which is not directly related to their basic strength; for example, the rate constant for dimethylamine is more than 30,000 times that for diisopropylamine though the latter is the stronger base. Evidence is adduced that a steric effect plays an important part in determining the rate constant. 
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