Health & Environmental Research Online (HERO)


Print Feedback Export to File
8456639 
Journal Article 
Preparation of esters of 1-bromomethylcyclopropylcarbinol 
D'Yachenko, AI; Lukina, MY 
1968 
1 
Bulletin of the Academy of Sciences of the USSR. Division of Chemical Science
ISSN: 0568-5230 
Kluwer Academic Publishers-Plenum Publishers 
17 
3 
651-653 
English 
1. The addition of carboxylic acid bromides to 2-oxaspiro-[3,2]-hexane proceeds without rearrangement, leading to the corresponding esters of 1-bromomethylcyclopropylcarbinol. 2. The addition of HCl to 2-oxaspiro-[3,2]-hexane at 0° leads to 1-chloromethylcyclopropylcarbinol, and the analogous reaction with HBr to a mixture containing 1-bromomethylcyclopropylcarbinol. 3. Prepared for the first time are the acetate, fluoroacetate, and trifluoroacetate of 1-bromomethylcyclopropylcarbinol. © 1968 Consultants Bureau.