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8458762 
Journal Article 
Chemically and Physically Modified Flame-Retardant Silicone-Acrylic Emulsion Adhesive for Electrostatic Flocking 
Zhou, Man; Zhai, S; Song, T; Zhao, H; Fan, Z; Ge, F; Zhao, Y; Xu, Bi; Cai, Z; , 
2020 
Yes 
Journal of Inorganic and Organometallic Polymers and Materials
ISSN: 1574-1443
EISSN: 1574-1451 
SPRINGER 
DORDRECHT 
4342-4349 
WOS:000546505800001 
The acrylic adhesives with the flame-retardant property are necessary to meet the safety requirement in electrostatic flocking. In this study, acrylic emulsion chemically modified with phosphorus and silicone, PSE, with core-shell structure, was synthesized by introducing the vinyl silicone oil and phosphor-containing monomer (PAM-100) onto the molecular chain of acrylic ester polymer in the core and shell layer, respectively. Subsequently, the silicone-acrylic adhesive with flame retardation (FR-SA) was prepared by mixing PSE with inorganic flame-retardant, Al(OH)(3). The acrylic adhesive obtains the excellent flame retardation under a low addition of Al(OH)(3)when the ratio of PAM-100 is 5%, while the commercial adhesive needs a high addition of the inorganic flame retardant to realize the satisfactory performance. FR-SA in this work has a great potential application as intrinsically flame-retardant electrostatic flocking adhesive.