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HERO ID
8493013
Reference Type
Journal Article
Title
Palladium-catalyzed aerobic oxidative direct esterification of alcohols
Author(s)
Liu, C; Wang, J; Meng, L; Deng, Y; Li, Y; Lei, A
Year
2011
Is Peer Reviewed?
Yes
Journal
Angewandte Chemie (International Edition)
ISSN:
1433-7851
EISSN:
1521-3773
Volume
50
Issue
22
Page Numbers
5144-5148
Language
English
DOI
10.1002/anie.201008073
Abstract
One step from alcohol to ester: A palladium-catalyzed oxidative esterification of various benzylic alcohols with methanol and long-chain aliphatic alcohols was carried out in the presence of molecular oxygen as the oxidant (see scheme). By considering the effects of substitution and potential mechanistic pathways, the applicability of this method to a range of different substrates was shown. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
Keywords
aerobic oxidation; alcohols; aldehydes; oxidative esterification; palladium
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