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8528849 
Journal Article 
Local Environments of Dilute Activator Ions in the Solid-State Lighting Phosphor Y3-xCexAl5O12 
George, NC; Pell, AJ; Dantelle, G; Page, K; Llobet, A; Balasubramanian, M; Pintacuda, G; Chmelka, BF; Seshadri, Ram; , 
2013 
Yes 
Chemistry of Materials
ISSN: 0897-4756
EISSN: 1520-5002 
AMER CHEMICAL SOC 
WASHINGTON 
3979-3995 
WOS:000326209200007 
The oxide garnet Y3Al5O12 (YAG), when substituted with a few percent of the activator ion Ce3+ to replace Y3+, is a luminescent material that is nearly ideal for phosphor-converted solid-state white lighting. The local environments of the small number of substituted Ce3+ ions are known to critically influence the optical properties of the phosphor. Using a combination of powerful experimental methods, the nature of these local environments is determined and is correlated with the macroscopic luminescent properties of Ce-substituted YAG. The rigidity of the garnet structure is established and is shown to play a key role in the high quantum yield and in the resistance toward thermal quenching of luminescence. Local structural probes reveal compression of the Ce3+ local environments by the rigid YAG structure, which gives rise to the unusually large crystal-field splitting, and hence yellow emission. Effective design rules for finding new phosphor materials inferred from the results establish that efficient phosphors require rigid, highly three-dimensionally connected host structures with simple compositions that manifest a low number of phonon modes, and low activator ion concentrations to avoid quenching.