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Citation
Tags
HERO ID
853549
Reference Type
Journal Article
Title
Structural characterization of a copper nitrosyl complex with a {CuNO}10 configuration
Author(s)
Wright, AM; Wu, G; Hayton, TW
Year
2010
Is Peer Reviewed?
Yes
Journal
Journal of the American Chemical Society
ISSN:
0002-7863
EISSN:
1520-5126
Volume
132
Issue
41
Page Numbers
14336-14337
Language
English
PMID
20879729
DOI
10.1021/ja105930b
Web of Science Id
WOS:000283276800006
Abstract
The synthesis and characterization of a {CuNO}(10) complex, namely, [Cu(CH(3)NO(2))(5)(NO)][PF(6)](2), has been achieved by the addition of [NO][PF(6)] to copper metal powder in the presence of nitromethane. In the solid state, this complex exhibits a bent Cu-N-O moiety [Cu-N-O = 121.0(3)°] and a long Cu-N bond. This complex readily reacts with mesitylene to form [mesitylene, NO][PF(6)] and [Cu(η(2)-1,3,5-Me(3)C(6)H(3))(2)][PF(6)] by transfer of NO(+) to the mesitylene ring.
Tags
IRIS
•
Nitrate/Nitrite
Supplemental LitSearch Update 1600-2015
WoS
New to project
•
Trimethylbenzenes (Interagency Science Discussion Draft)
Primary Literature Search
Primary Literature Search- Exclusion
Excluded by Journal
Chemistry or Physical or Engineering
•
Trimethylbenzenes (TMB)
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