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8544355 
Journal Article 
Color tunable dual-phase transparent glass ceramics for warm white light-emitting diodes 
Chen, D; Xu, Wei; Zhou, Y; Zhong, J; Li, S; , 
2017 
Journal of Materials Chemistry C
ISSN: 2050-7526
EISSN: 2050-7534 
ROYAL SOC CHEMISTRY 
CAMBRIDGE 
738-746 
WOS:000394577000029 
Currently, Ce3+: Y3Al5O12 phosphor converted white light-emitting diodes suffer from a deficiency of adequate red components and easy aging of the organic silicone matrix. Herein, Ce3+/Mn2+/Si4+: Y3Al5O12 phosphors were synthesized via a traditional solid-state reaction and they can emit intense red luminescence, which is attributed to the Mn2+: T-4(1) -> (6)A(1) spin-forbidden transition under the excitation of blue light via efficient energy transfer from Ce3+ to Mn2+. Temperature-dependent emission spectra and luminescent decay curves evidence that Mn2+ activators partition into both the Al3+ octahedral and Y3+ dodecahedral sites, whereas the Si4+ sites located in the Al3+ tetrahedral site are charge compensators. Furthermore, inorganic Ce3+: Y3Al5O12 and Ce3+/Mn2+/Si4+: Y3Al5O12 dual-phase transparent glass ceramics were successfully fabricated via a low-temperature co-sintering technique to replace the phosphor in organic silicone as a color converter, and red to yellow tunable luminescence can be easily achieved by controlling the content of red phosphor in the glass matrix. Note that by combining the fabricated dual-phase glass ceramics with the InGaN blue chip, warm white light-emitting diodes with a superior optical performance and excellent heat-resistance stability were successfully constructed.