Health & Environmental Research Online (HERO)


Print Feedback Export to File
8585903 
Journal Article 
A rhodium peroxido complex in Mono-, Di-, and peroxygenation reactions 
Meier, G; Braun, T 
2011 
Yes 
Angewandte Chemie (International Edition)
ISSN: 1433-7851
EISSN: 1521-3773 
50 
14 
3280-3284 
English 
A versatile peroxido complex: The rhodium peroxido complex 1, which can be prepared from 2 and dioxygen, participates in mono-oxygenation of a phosphine and dioxygenation of tetrakis(dimethylamino)ethylene to give, respectively, phosphine oxide and a urea derivative, while peroxygenation of 9,10-dimethylanthracene to yield the anthracene endoperoxide takes place in the presence of dioxygen and substoichiometric amounts of 1 (see scheme). Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim. 
fluorinated ligands; oxygen; oxygenation; peroxido ligands; rhodium