Health & Environmental Research Online (HERO)


Print Feedback Export to File
8586716 
Journal Article 
Highly Activated Second-Generation Grubbs-Hoveyda Catalyst Driven by Intramolecular Steric Strain 
Kobayashi, Y; Miyazaki, H; Inukai, S; Takagi, C; Makino, R; Shimowaki, K; Igarashi, R; Sugiyama, Y; Nakamura, S; Matsugi, M 
2016 
1 
Synlett
ISSN: 0936-5214
EISSN: 1437-2096 
Georg Thieme Verlag 
27 
16 
2352-2356 
English 
Various Grubbs-Hoveyda second-generation catalysts activated by intramolecular steric strain were prepared. The variant bearing a 9-anthracenyl group in the ligand moiety exhibited the highest catalytic activity. The new anthracenyl-type-activated catalyst was used in a ring-closing metathesis reaction to effectively provide a 4-substituted product effectively. © Georg Thieme Verlag Stuttgart New York - Synlett 2016. 
activation; catalyst; ligand; metathesis; steric strain