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HERO ID
8586990
Reference Type
Journal Article
Title
Unusual reactivity of DMAD (dimethyl acetylenedicarboxylate) with N-alkyl-9-anthracenemethanamine
Author(s)
Devassia, T; Prathapan, S; Unnikrishnan, PA
Year
2018
Publisher
Elsevier B.V.
Volume
17-18
Page Numbers
9-12
Language
English
DOI
10.1016/j.cdc.2018.07.004
Abstract
This communication deals with the synthesis and characterization of a few N-alkyl-9-anthracenemethanamines and their reaction with dimethyl acetylenedicarboxylate (DMAD). Irrespective of reaction conditions, the corresponding dimethyl 2-((anthracen-9-ylmethyl)-amino)fumarates arising through a Michael-type addition reaction were exclusively formed in the reaction between these secondary amines and DMAD. © 2018
Keywords
Anthracenemethanamine; DielsâAlder reaction; DMAD; Michael addition
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