Study of the low-temperature interaction of iron vapors with methyl derivatives of benzene by IR spectroscopy | Health & Environmental Research Online (HERO)

Health & Environmental Research Online (HERO)

Print Feedback Export to File

This record has one attached file:

Citation
Tags

HERO ID

859375

Reference Type

Journal Article

Title

Study of the low-temperature interaction of iron vapors with methyl derivatives of benzene by IR spectroscopy

Author(s)

Kurtikyan, TS; Aleksanyan, VT

Year

1978

Is Peer Reviewed?

Journal

Russian Chemical Bulletin
ISSN: 1066-5285
EISSN: 1573-9171

Volume

Issue

Page Numbers

2034

Language

English

DOI

10.1007/BF00946521

Web of Science Id

WOS:A1978GY76200019

URL

https://www.scopus.com/inward/record.uri?eid=2-s2.0-34250282982&doi=10.1007%2fBF00946521&partnerID=40&md5=014e21a0c82620e9ffa18d436e5032c2
Exit

Abstract

1.Study has been made of the interaction of chromium and iron vapors with toluene, mesitylene, and durol on liquid-nitrogen cooled surfaces. IR spectroscopy has been used to confirm the low-temperature formation of previously unknown bisarene iron (0) complexes. Decomposition temperatures have been determined for these compounds.2.The fact that the skeletal vibration frequencies of the various bisarene chromium complexes were essentially identical suggests that the strength of the metal-ligand bond increases as more and more methyl substituents are introduced into the benzene ring.